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hydraulika-i-pneumatyka: Tetraethyllead

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Of the some 33,000 substances in total screened, lead was found to be the most effective antiknock agent, in that it necessitated the smallest concentrations necessary; a treatment of 1 part TEL to 1300 parts gasoline by weight is sufficient to suppress detonation.
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It was widely used as a fuel additive for much of the 20th century, first being mixed with gasoline beginning in the 1920s.
Pełniejszy materiał źródłowy / excerpt
Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb(C2H5)4. It was widely used as a fuel additive for much of the 20th century, first being mixed with gasoline beginning in the 1920s. This "leaded gasoline" had an increased octane rating that allowed engine compression to be raised substantially and in turn increased vehicle performance and fuel economy. TEL was first synthesized by German chemist Carl Jacob Löwig in 1853. American chemical engineer Thomas Midgley Jr., who was working for the U.S. corporation General Motors, was the first to discover its effectiveness as a knock inhibitor on 9 December 1921, after spending six years attempting to find an additive that was both highly effective and inexpensive. Of the some 33,000 substances in total screened, lead was found to be the most effective antiknock agent, in that it necessitated the smallest concentrations necessary; a treatment of 1 part TEL to 1300 parts gasoline by weight is sufficient to suppress detonation. The four ethyl groups in the compound served to dissolve the active lead atom within the fuel. When injected into the combustion chamber, tetraethyllead decomposed upon heating into ethyl radicals, lead, and lead oxide. The lead oxide scavenges radicals and therefore inhibits a flame from developing until full compression has been achieved, allowing…
Kategoria: historia
Rodzina: historia
Jakość źródła: 65/100
Próby weryfikacji: 3
Notatka fact-checku: Fact-check 3.0-content-aware: no sufficient claim-bound corroboration after 3 healthy attempts. Scope=verify the factual claim. Required independent sources=2; stored evidence groups=0. Provider/API errors did not consume attempts. | Fact-check 4.3.2: research wznowiony bez zdejmowania HOLD. Poprzednia metoda: factcheck-300-content-aware. | Fact-check 4.3.2: research wznowiony bez zdejmowania HOLD. Poprzednia metoda: factcheck-weekly-research-432.

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African Journals Online (AJOL)pomocniczeniezależne

Evidence: 21 • authority: 80

Lead concentrations in food crops found along roadsides in some municipal environments in Nigeria

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Wikipedia ENpomocnicze

Evidence: — • authority: 72

Gasoline (North American English) or petrol (in other English-speaking countries) is a petrochemical product, a transparent, yellowish and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. It is chemically composed of organic compounds derived from the fractional distillation of petroleum and later chemically enhanced with gasoline additives. It is a high-volume profitable product produced in crude oil refineries. The ability of a particular gasoline blend to resist premature ignition (which causes knocking and reduces efficiency in reciprocating engines) is measured by its octane rating or performance number. Tetraethyl lead was once widely used to inc…

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Wikipedia ENpomocnicze

Evidence: — • authority: 72

An antiknock agent (or knock inhibitor) is a gasoline additive used to reduce engine knocking and increase the fuel's octane rating by raising the temperature and pressure at which auto-ignition occurs. The mixture known as gasoline or petrol, when used in high compression internal combustion engines, has a tendency to knock (also called "pinging" or "pinking") and/or to ignite early before the correctly timed spark occurs (pre-ignition, refer to engine knocking). Notable early antiknock agents, especially tetraethyllead, added to gasoline included large amounts of toxic lead. The chemical was responsible for global negative impacts on health, and the phase out of leaded gasoline from the 1…

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SAE Internationalpomocnicze

Evidence: — • authority: 88

Antiknock Performance of Gasoline Substitutes and their Effects on Gasoline Properties. <div class="htmlview paragraph">This paper describes some of the recent work carried out in our laboratory regarding the effects of novel oxygen and nitrogen containing compounds on the antiknock quality of unleaded gasoline and their effects on some other gasoline properties. In particular, the research included Research Octane Number (RON) measurements and the evaluation of the effects of the most effective antiknock compounds on Dry Vapour Pressure Equivalent (DVPE), distillation temperatures, aromatic content, olefins, and oxygen content. Emphasis was given in studying chemical structures that can be…

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Wikipedia ENpomocnicze

Evidence: — • authority: 72

Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb(C2H5)4. It was widely used as a fuel additive for much of the 20th century, first being mixed with gasoline beginning in the 1920s. This "leaded gasoline" had an increased octane rating that allowed engine compression to be raised substantially and in turn increased vehicle performance and fuel economy. TEL was first synthesized by German chemist Carl Jacob Löwig in 1853. American chemical engineer Thomas Midgley Jr., who was working for the U.S. corporation General Motors, was the first to discover its effectiveness as a knock inhibitor on 9 December 1921, after spending six yea…

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